Nitrogen Oxides Research Articles

Atmospheric Oxidation Capacity Elevated during 2020 Spring Lockdown in Chengdu, China: Lessons for Future Secondary Pollution Control.

This study presents the measurement of photochemical precursors during the lockdown period from January 23, 2020, to March 14, 2020, in Chengdu in response to the coronavirus (COVID-19) pandemic. To derive the lockdown impact on air quality, the observations are compared to the equivalent periods in the last 2 years. An observation-based model is used to investigate the atmospheric oxidation capacity change during lockdown. OH, HO2, and RO2 concentrations are simulated, which are elevated by 42, 220, and 277%, respectively, during the lockdown period, mainly due to the reduction in nitrogen oxides (NOx). However, the radical turnover rates, i.e., OH oxidation rate L(OH) and local ozone production rate P(O3), which determine the secondary intermediates formation and O3 formation, only increase by 24 and 48%, respectively. Therefore, the oxidation capacity increases slightly during lockdown, which is partly attributed to unchanged alkene concentrations. During the lockdown, alkene ozonolysis seems to be a significant radical primary source due to the elevated O3 concentrations. This unique data set during the lockdown period highlights the importance of controlling alkene emission to mitigate secondary pollution formation in Chengdu and may also be applicable in other regions of China given an expected NOx reduction due to the rapid transformation to electrified fleets in the future.

Aluminum dynamics in nitrogen‐saturated Andisols in Tokyo

AbstractThe debate over whether forests around the Tokyo metropolitan area are nitrogen (N) saturation persists, as atmospheric N deposition in throughfall has decreased. This decrease is evidenced by a notable decline in samples collected in the 1990s (especially 1991–1992 and 1995). This decline can be attributed to a reduction in nitrogen oxide (NOx) emissions from automobiles. The acidity derived from N deposition can increase aluminum (Al) mobility. We conducted a monitoring study from September 2010 to December 2021 to elucidate the effects of decreased N deposition on Al concentrations and flux in a forested Andisol. Throughfall and soil‐percolated water samples were collected under stands of Japanese cedar and Japanese cypress in Hachioji, Tokyo (Field Museum Tamakyuryo). Major inorganic ions were determined by ion chromatography. Total Al concentrations were determined using atomic absorption spectrometry after concentration under acidic conditions. Aluminum and nitrate () concentrations were significantly correlated in the both Japanese cedar and Japanese cypress stands. In the case of the Japanese cedar stand, Al concentrations tended to decrease over time from November 2010 to May 2015. Based on stepwise multiple regression analysis, acid load associated with N transformation ([H+]load) was chosen as the sole factor affecting Al mobilization in the Japanese cedar stand. Decreased N deposition affects Al dynamics via a decrease in [H+]load.

Effect of CO2 Gasification on Nitrogen Oxide Emission in Oxy-Fuel Combustion.

Due to the cumulative effect of the recycled flue gas in oxy-fuel combustion, the reduction of NO has become the focus of research in which the role of CO2 gasification has a nonnegligible effect. In this article, the heterogeneous gasification mechanisms of CO2 on coal char during oxy-fuel combustion were studied by density functional theory and transition-state theory. The zigzag char model and char(N) model were selected to investigate the CO2 adsorption and gratification reactions at the molecular level. By comparison, the CO2 gasification reaction is preferred to occur on the zigzag char model with a reduction in the energy barrier and an increase in the reaction rate. When considering char nitrogen conversion, the gasification reaction is more prone to releasing NO first, leading to the contraction of the aromatic ring and the generation of CO at high temperatures. Therefore, the study further highlights the promoting role of CO2 gasification on the homogeneous and heterogeneous reduction of NO, which is mainly reflected in the reduction effect of CO. Moreover, it also accelerates the consumption of coal char and NO formation, which is favorable for the reduction reactions to a certain extent.

Impact of air pollution and climate change on mental health outcomes: an umbrella review of global evidence.

The impact of air pollution and climate change on mental health has recently raised strong concerns. However, a comprehensive overview analyzing the existing evidence while addressing relevant biases is lacking. This umbrella review systematically searched the PubMed/Medline, Scopus and PsycINFO databases (up to June 26, 2023) for any systematic review with meta-analysis investigating the association of air pollution or climate change with mental health outcomes. We used the R metaumbrella package to calculate and stratify the credibility of the evidence according to criteria (i.e., convincing, highly suggestive, suggestive, or weak) that address several biases, complemented by sensitivity analyses. We included 32 systematic reviews with meta-analysis that examined 284 individual studies and 237 associations of exposures to air pollution or climate change hazards and mental health outcomes. Most associations (n=195, 82.3%) involved air pollution, while the rest (n=42, 17.7%) regarded climate change hazards (mostly focusing on temperature: n=35, 14.8%). Mental health outcomes in most associations (n=185, 78.1%) involved mental disorders, followed by suicidal behavior (n=29, 12.4%), access to mental health care services (n=9, 3.7%), mental disorders-related symptomatology (n=8, 3.3%), and multiple categories together (n=6, 2.5%). Twelve associations (5.0%) achieved convincing (class I) or highly suggestive (class II) evidence. Regarding exposures to air pollution, there was convincing (class I) evidence for the association between long-term exposure to solvents and a higher incidence of dementia or cognitive impairment (odds ratio, OR=1.139), and highly suggestive (class II) evidence for the association between long-term exposure to some pollutants and higher risk for cognitive disorders (higher incidence of dementia with high vs. low levels of carbon monoxide, CO: OR=1.587; higher incidence of vascular dementia per 1 μg/m3 increase of nitrogen oxides, NOx: hazard ratio, HR=1.004). There was also highly suggestive (class II) evidence for the association between exposure to airborne particulate matter with diameter ≤10μm (PM10) during the second trimester of pregnancy and the incidence of post-partum depression (OR=1.023 per 1 μg/m3 increase); and for the association between short-term exposure to sulfur dioxide (SO2) and schizophrenia relapse (risk ratio, RR=1.005 and 1.004 per 1 μg/m3 increase, respectively 5 and 7 days after exposure). Regarding climate change hazards, there was highly suggestive (class II) evidence for the association between short-term exposure to increased temperature and suicide- or mental disorders-related mortality (RR=1.024), suicidal behavior (RR=1.012), and hospital access (i.e., hospitalization or emergency department visits) due to suicidal behavior or mental disorders (RR=1.011) or mental disorders only (RR=1.009) (RR values per 1°C increase). There was also highly suggestive (class II) evidence for the association between short-term exposure to increased apparent temperature (i.e., the temperature equivalent perceived by humans) and suicidal behavior (RR=1.01 per 1°C increase). Finally, there was highly suggestive (class II) evidence for the association between the temporal proximity of cyclone exposure and severity of symptoms of post-traumatic stress disorder (r=0.275). Although most of the above associations were small in magnitude, they extend to the entire world population, and are therefore likely to have a substantial impact. This umbrella review classifies and quantifies for the first time the global negative impacts that air pollution and climate change can exert on mental health, identifying evidence-based targets that can inform future research and population health actions.

Tracking social-economic system nitrogen flow in China for emissions reduction and efficiency improvement

The increasing human demand have driven intensive reactive nitrogen (Nr) use, leading to high emissions and low efficiency in entire social-economic system. Herein, we accomplished a social-economic Nr flow model to trace the multi-sectorial Nr use, efficiency, and emissions in China from 1980 to 2020. The results showed that Nr use intensity increased 3.1-fold within four decades, with the decreasing proportions of Nr recovery from 32.7 % to 16.8 %. The Nr use pathways of production, consumption and waste management stages showed low resources use efficiency in agriculture and industrial production, high degree of consumption loss, insufficient waste treatment characteristics currently. Nr emissions peaked in 2012 and declined 12.7 % to 2020 owing to the nitrogen oxides control and mitigating overuse of fertilizers, and will continuously decrease under strategies in 2040 (41.7 % compared with 2012), indicating the large potential for emission reduction and efficiency improvement in next few decades.

Method and application of surface modification of Cerium dioxide

Airborne pollutants, such as nitrogen oxides (NOx), and waterborne contaminants, including heavy metals, dyes, and other pollutants, pose substantial environmental threats and jeopardize human health. Additionally, certain limitations have hindered the widespread application of some batteries, primarily attributed to elevated operating temperatures and the decreasing use of fossil fuels. In response to these challenges, cerium dioxide (CeO2) nanoparticles have garnered considerable attention due to their unique and advantageous physical and chemical properties. Furthermore, the incorporation of CeO2 into various coating materials has demonstrated the potential to significantly enhance their performance. In the realm of biotechnology, research into CeO2 nanoparticles continues to expand, encompassing a range of applications such as the scavenging of reactive oxygen species (ROS) in biological systems, the development of anti‐inflammatory agents, and cancer research. Nevertheless, in these diverse applications, CeO2 still exhibits certain limitations that hinder the achievement of desired outcomes. The modification of CeO2 nanoparticles presents a promising avenue to address these limitations, thereby improving their overall efficacy. As such, this review aims to comprehensively compare and summarize various methods for the modification of CeO2 nanoparticles, elucidate their practical applications, and provide insights into the potential challenges and future prospects in this field.This article is protected by copyright. All rights reserved.

Water extraction in aero gas turbines for contrail mitigation

Abstract Water vapour and particles in aero engine exhaust can give rise to condensation trails (contrails) in the wake of aircrafts, and recent studies suggest that persistent contrails and contrail cirrus account for circa 50% of the total aviation-derived radiative forcing (RF). The Schmidt-Appleman criterion is widely used to qualitatively predict the formation of contrails. The criterion indicates that the formation of contrails is affected by both aero engine exhaust and ambient air conditions and can therefore provide the theoretical basis to devise contrail mitigation strategies and further allows quantitative assessment of these strategies. This work focuses on water extraction from the aircraft engine exhaust for contrail mitigation. The fuel water emission index ( ${\rm{E}}{{\rm{I}}_{{{\rm{H}}_2}{\rm{O}}}}$ ) is one of the key factors that determines whether persistent contrails form or not. It indicates the amount of water produced for every kg of fuel burnt. Research has indicated that water extraction from the exhaust of the aero engine has been considered for Nitrogen oxides (NOx) reduction, but not for contrail mitigation. Assuming that water extraction is indeed possible, the emphasis of this work will therefore be on understanding how much water is needed to be extracted for contrail mitigation depending on the altitude and the relative humidity (RH), with the aim to carry out a meaningful study on the mitigation of persistent contrails and contrail cirrus to enable a fast and considerable reduction in aviation-derived RF.

Quality of Carbon Emissions Disclosure on Corporate Sustainability Report Gojek Period 2020 and Goto Period 2021 – 2022

The high level of air pollution which is increasing from year to year causes air quality to decline. One of the causes of the increase in air is the growth in the number of motorized vehicles which causes an increase in the amount of emissions released in the form of Carbon Monoxide (CO), Hydrocarbons (HC), Nitrogen Oxide (NO). This shows that climate change is occurring. Climate change is one of the environmental problems that is currently of concern to stakeholders. The Carbon Disclosure Project (CDP) is a non-profit organization that operates focused on addressing environmental issues. CDP works by publishing information sheets which are useful as a guide for companies to disclose greenhouse gas (GHG) emissions resulting from the company's business activities. The company publishes a sustainability report which reveals carbon emissions. GoTo is a merger between Gojek and Tokopedia where in 2020 Gojek published a sustainability report. Scoring of carbon emission disclosures both quantitatively and qualitatively was carried out in this research. During the 2020-2021 period, the highest level of suitability and quality of disclosure was obtained by GoTo. Quantitatively, the climate change category has high disclosure quality. Qualitatively, the GHG emissions calculation category has the highest disclosure quality.

Measurement-based carbon intensity of US offshore oil and gas production

Abstract The United States (US) produces oil and gas from six offshore regions: the North Slope of Alaska, Cook Inlet in Alaska, offshore California, and three Gulf of Mexico (GOM) sub-regions: state shallow, federal shallow, and deep waters. Measurement-based assessment of direct greenhouse gas emissions from this production can provide real-world information on carbon emissions to inform decisions on current and future production. In evaluating the climate impact of production, the Carbon Intensity (CI, the ratio of greenhouse gases emitted compared to the energy of fuels produced) is often used, though it is rarely quantified with measurements. Here, we complete an observational evaluation of the US offshore sector and present the largest current set of measurement-based CIs. We collected airborne measurements of methane, carbon dioxide, and nitrogen oxides from the North Slope, Cook Inlet, and California and combined with prior GOM results. For Alaska and California, we found emissions agree with facility-level inventories, however, the inventories miss some facilities. The US offshore CI, on a 100-year GWP basis, is 5.7 gCO2e/MJ[4.5, 6.8, 95% confidence interval]. This is greater than double the CI based on the national US inventory, with the discrepancy attributed primarily to methane emissions from GOM shallow waters, with a methane dominated CI of 16[12, 22] for GOM federal shallow waters and 43[25-65] for state shallow waters. Regional intensities vary, with carbon dioxide emissions largely responsible for CI on the North Slope 11[7.5, 15], in Cook Inlet 22[13, 34], offshore California 7.2[3.2, 13], and in GOM deep waters 1.1[1.0, 1.1]. These observations indicate offshore operations outside of the GOM in the US have modest methane emissions, but the CI can still be elevated due to direct carbon dioxide emissions. Accurate assessment of different offshore basins, with differing characteristics and practices, is important for the climate considerations of expanded production.

Automatic Fuel Flow Regulation System for the Combustion Chamber under Varying Operating Conditions Based on a Neural Nitrogen Oxide Sensor

Automatic Fuel Flow Regulation System for the Combustion Chamber under Varying Operating Conditions Based on a Neural Nitrogen Oxide Sensor

Projecting non-communicable diseases attributable to air pollution in the climate change era: a systematic review

ObjectivesClimate change is a major global issue with significant consequences, including effects on air quality and human well-being. This review investigated the projection of non-communicable diseases (NCDs) attributable to air...

Effects of Ethanol addition to Diesel-Biodiesel blends on the CI engine characteristics

This research work investigates the effects of adding ethanol to biodiesel-diesel blends on the performance and emissions of a single-cylinder, four-stroke, air-cooled compression-ignition engine. The engine was half loaded within a speed range 1000-2500 rpm. Four different fuel blends are considered: B0 (no biodiesel or ethanol), B10 (10% biodiesel), B10E2.5 (10% biodiesel with 2.5% ethanol), and B10E5 (10% biodiesel with 5% ethanol). The findings show that adding biodiesel slightly affects the engine power at low and medium speeds but increases power by approximately 6% at high speeds. Ethanol addition has a more significant impact, with an increase in engine power of 16% at 1700 rpm and 13% at 2500 rpm for 2.5% and 5% ethanol blends, respectively. All blends show an increase in brake mean effective pressure (BMEP) compared to B0, with the maximum enhancement observed in B10 with an average increase of 13% across all speeds. Specific fuel consumption is reduced with both biodiesel and ethanol addition, with a slight advantage for biodiesel, particularly at low and medium speeds. Thermal efficiency shows a reverse behaviour, with a small negative impact of ethanol addition. Biodiesel addition significantly increases carbon monoxide (CO) emissions, reaching an average of 190% across all speeds. However, adding ethanol helps mitigate this increase, especially at low and medium speeds, with an average decrease of 32% for 2.5% ethanol blend compared to B0. Carbon dioxide (CO2) and nitrogen oxides (NOx) emissions are reduced with biodiesel addition, and further reduced with ethanol addition. Overall, CO2 and NOx emissions are reduced with both biodiesel and ethanol addition.

Urban air pollution evaluation in downtown streets of a medium-sized Latin American city using AERMOD dispersion model.

The transport sector is considered the largest contributor of air pollutants in urban areas, mainly on-road vehicles, affecting the environment and human health. Bahía Blanca is a medium-sized Latin American city, with high levels of traffic in the downtown area during peak hours. In this regard, it is necessary to analyze air pollution using an air quality model considering that there are no air pollutant measurements in the central area. Furthermore, this type of study has not been carried out in the region and since the city is expected to grow, it is necessary to evaluate the current situation in order to make effective future decisions. In this sense, the AERMOD model (US-EPA version) and the RLINE source type were used in this work. This study analyzes the variations of pollutant concentrations coming from mobile sources in Bahía Blanca's downtown area, particularly carbon monoxide (CO) and nitrogen oxides (NOx) during the period Jul-2020 to Jun-2022. It is interesting to note the results show the maximum concentration values detected are not directly associated with maximum levels of vehicle flow or emission rates, which highlights the importance of meteorological parameters in the modeling. In addition, alternative scenarios are proposed and analyzed from a sustainable approach. Regarding the scenario analysis, it can be concluded that diesel vehicles have a large influence on NOx emissions. Moreover, restrictions as strict as those proposed for a Low Emission Zone would be less applicable in the city than alternative temporary measures that modify traffic at peak hours.

PORT INJECTION OF DIESEL, BIODIESEL, AND PETROL IN A COMPRESSION IGNITION DIRECT INJECTION DIESEL ENGINE TO MITIGATE NITROGEN OXIDES AND SOOT EMISSIONS

The internal combustion engine is critical to modern society’s development. Spark ignition engine (SI) and compression ignition engine (CI) now use gasoline and diesel as their primary fuels. As a result of burning these fuels, significant amounts of pollutants are released into the atmosphere, resulting in environmental issues. Internal combustion (IC) engines are widely acknowledged as a significant source of environmental air pollution. The engine’s fuel oxidation process not only produces useful power, but also produces significant amounts of pollutant emissions such as carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxide (NOx ), and particulate matter (PM). When developing a new combustion process, consideration must be given to: lean homogeneous air-fuel mixture, increased compression ratio, and total and instantaneous combustion, all of which result in Port Injection Compression Ignition (PICI), that is a highly efficient and clean method of combustion. The goal of this research is to conduct an experimental investigation of PICI process of compression in a Premixed Charge Compression Ignition (PCCI) mode with Pilot Injection (PI) as the combustion activator. It was found that when compared to the conventional mode, the PICI mode produces cooler exhaust gas temperatures. Temperatures were lower in the PICI mode with biodiesel and petrol as secondary and primary fuels than in the PICI mode with other fuel combinations. In the PICI mode, the HC emission decreases at higher load with all fuels. In the biodiesel conventional mode, HC emission is minimum than in other modes. For all modes of operation, the specific fuel consumption has reduced with load. Diesel and gasoline have the lowest specific fuel consumption as primary and secondary fuels, respectively. Fuel usage in the PICI mode is lower than in the normal mode.

Detonation properties and nitrogen oxide production in ammonia–hydrogen–air mixtures

Ammonia is a promising compound for chemical storage of renewable energy produced from non-continuous sources. However, the low reactivity of ammonia requires to use ammonia–hydrogen blends as a fuel for combustion applications. The present study corresponds to a first numerical assessment of the potential of ammonia–hydrogen–air mixtures as reactive mixtures for detonation engine applications. Both ideal and curved detonation models were employed to calculate the detonation properties, entropy production, and NOx production for mixtures with varying amounts of ammonia and hydrogen under a wide range of initial thermodynamics conditions. Interestingly, our calculations show that the entropy production and the amount of nitrogen oxides produced at the Chapman–Jouguet state respectively decreases and increases with the proportion of hydrogen in the ammonia–hydrogen blend. These aspects could have a great impact on engine efficiency and air pollution and should be considered with care. Our results also demonstrate that only mixtures with relatively low amounts of ammonia, i.e., XNH3 lower than 0.25 of the fuel blend, can be employed for detonation engine applications.

Quantifying the contributions of meteorology, emissions, and transport to ground-level ozone in the Pearl River Delta, China

Ozone pollution presents a growing air quality threat in urban agglomerations in China. It remains challenge to distinguish the roles of emissions of precursors, chemical production and transportations in shaping the ground-level ozone trends, largely due to complicated interactions among these 3 major processes. This study elucidates the formation factors of ozone pollution and categorizes them into local emissions (anthropogenic and biogenic emissions), transport (precursor transport and direct transport from various regions), and meteorology. Particularly, we attribute meteorology, which affects biogenic emissions and chemical formation as well as transportation, to a perturbation term with fluctuating ranges. The Community Multiscale Air Quality (CMAQ) model was utilized to implement this framework, using the Pearl River Delta region as a case study, to simulate a severe ozone pollution episode in autumn 2019 that affected the entire country. Our findings demonstrate that the average impact of meteorological conditions changed consistently with the variation of ozone pollution levels, indicating that meteorological conditions can exert significant control over the degree of ozone pollution. As the maximum daily 8-hour average (MDA8) ozone concentrations increased from 20 % below to 30 % above the National Ambient Air Quality Standard II, contributions from emissions and precursor transport were enhanced. Concurrently, direct transport within Guangdong province rose from 13.8 % to 22.7 %, underscoring the importance of regional joint prevention and control measures under adverse weather conditions. Regarding biogenic emissions and precursor transport that cannot be directly controlled, we found that their contributions were generally greater in urban areas with high nitrogen oxides (NOx) levels, primarily due to the stronger atmospheric oxidation capacity facilitating ozone formation. Our results indicate that not only local anthropogenic emissions can be controlled in urban areas, but also the impacts of local biogenic emissions and precursor transport can be potentially regulated through reducing atmospheric oxidation capacity.

Dielectric Properties of Materials Used for Microwave-Based NOx Gas Dosimeters.

Nitrogen oxides (NOx), primarily generated from combustion processes, pose significant health and environmental risks. To improve the coordination of measures against excessive NOx emissions, it is necessary to effectively monitor ambient NOx concentrations, which requires the development of precise and cost-efficient detection methods. This study focuses on developing a microwave- or radio frequency (RF)-based gas dosimeter for NOx detection and addresses the optimization of the dosimeter design by examining the dielectric properties of LTCC-based (Low-Temperature Co-fired Ceramics) sensor substrates and barium-based NOx storage materials. The measurements taken utilizing the Microwave Cavity Perturbation (MCP) method revealed that these materials exhibit more pronounced changes in dielectric losses when storing NOx at elevated temperatures. Consequently, operating such a dosimeter at high temperatures (above 300 °C) is recommended to maximize the sensor signal. To evaluate their high-temperature applicability, LTCC substrates were analyzed by measuring their dielectric losses at temperatures up to 600 °C. In terms of NOx storage materials, coating barium on high-surface-area alumina resolved issues related to limited NOx adsorption in pure barium carbonate powders. Additionally, the adsorption of both NO and NO2 was enabled by the application of a platinum catalyst. The change in dielectric losses, which provides the main signal for an RF-based gas dosimeter, only depends on the stored amount of NOx and not on the specific type of nitrogen oxide. Although the change in dielectric losses increases with the temperature, the maximum storage capacity of the material decreases significantly. In addition, at temperatures above 350 °C, NOx is mostly weakly bound, so it will desorb in the absence of NOx. Therefore, in the future development of a reliable RF-based NOx dosimeter, the trade-off between the sensor signal strength and adsorption behavior must be addressed.

Association between ambient air pollution and biological aging among the middle-aged and older adults: a systematic review

Objective: To summarize and elucidate the impact of ambient air pollution on biological aging among middle-aged and older adults. Methods: "Air pollution""Biological age""Epigenetic age""Biological aging"and"Epigenetic aging", as well as specific names of air pollutants and biological age were used as search keywords. This study searched the databases of PubMed and Web of Science for eligible English articles and CNKI, CQVIP, Wanfang, CBM, CSTP and other Chinese databases for eligible Chinese articles from inception until June 30, 2023. The language was limited to Chinese and English. Results: Among the 14 included articles, five studies investigated the impact of air pollution on DNA methylation age using different algorithms, while six studies explored the relationship between air pollutants and telomere length. Six studies focused on frailty as an outcome, and an additional study revealed the relationship between fine particulate matter (PM2.5) and its components with composite indicator age (KDM age). The results indicated that, although different forms of biological ages were susceptible to different ambient air pollutants at different degrees, previous studies had consistently found that the increased levels of PM2.5 and one of its major components, black carbon (BC), could significantly accelerate the biological aging of middle-aged and older adults. Similar trends were observed with nitrogen oxides (NOx) and ozone (O3) but with relatively limited evidence. Conclusion: Major air pollutants could accelerate the biological aging of middle-aged and older adults.

Preparation of co-doped biochar to improve electron transfer and modulate 1O2 generation: Unraveling the radical-unradical mechanism

The aim of this paper is to investigate the catalytic activity, the mechanism on degrading tetracycline (TC) with co-doped biochar modifying with non-metallic heteroatoms and transition metal oxides in a persulfate (PS) system. To this end, we ingeniously prepared nitrogen and copper oxide co-doped biochar (CNB-500) and activated it with PS to develop a CNB-500-PS system that can efficiently degrade TC. Owing to constructing a multi-pathway electron transfer channel, the non-radical interaction-electron transfer in the system was enhanced; the surface charge distribution of the catalyst was broken, and its adsorption with dissolved oxygen in water was regulated towards induce the generation of singlet oxygen (1O2); the mechanism on radical-non-radical synergism was elucidated, and the possible degradation pathways for TC were speculated. Therefore, the CNB-500-PS system provides a new strategy for degrading antibiotics in water.

Simulation studies of pollutant emissions from road vehicles using models for inventories of pollutant emissions

Countries are obliged by international regulations to conduct annual pollutant emissions inventories. Road transport is one of the sectors for which an inventory of pollutant emissions is carried out. Determining pollutant emissions from road transport is possible only by modeling these emissions – that is why unified emission models are used. In this work, the COPERT and HBEFA INFRAS software are used to determine pollutant emissions characteristics for various vehicle traffic models. The article presents the principles of modeling pollutant emissions from road vehicles. The rules for qualifying road vehicles into elementary and cumulative categories have been systematized. Models of road vehicle traffic and ways of taking them into account in modeling pollutant emissions are presented. The following emissions of pollutants harmful to the health and life of living organisms are considered: carbon monoxide, non-methane volatile organic compounds, nitrogen oxides and total suspended particles. The trends of the national annual emissions of the tested pollutants in the years 2000 – 2020 and the results of simulation tests of pollutant emissions models are presented.